Direct Synthesis of Coordination and Organometallic Compounds

Written By A.D. Garnovskii
Direct Synthesis of Coordination and Organometallic Compounds
  • Publsiher : Elsevier
  • Release : 13 August 1999
  • ISBN : 9780080530444
  • Pages : 244 pages
  • Rating : 4/5 from 21 reviews
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Read or download book entitled Direct Synthesis of Coordination and Organometallic Compounds written by A.D. Garnovskii which was release on 13 August 1999, this book published by Elsevier. Available in PDF, EPUB and Kindle Format. Book excerpt: This book is devoted to the interaction between elemental metals and (in)organic ligands in different reaction conditions. Metals could be activated for further reactions as cryosynthesis, electrosynthesis and tribosynthesis, some of them with or without ultrasonic and microwave treatment. The kinetics of metal dissolution in various non-aqueous media is discussed in detail. Many methods are used nowadays to synthesize coordination compounds. Metal complexes are obtained mainly by the direct interaction of the components (the ligands and a source of the complex-forming metal), as a result of ligand and metal exchange, and under the conditions of template synthesis, which also include the method of nascent reagents. In these methods the source of the metal is either its salts or carbonyls. At the same time, it has long been known that coordination compounds may be obtained as a result of direct synthesis from zero-valent metals. Methods for the synthesis of complex compounds under the conditions of gas-phase reactions, oxidative dissolution of zero-valent metals in non-aqueous media, and in the solid phase have been developed. These methods have become the basis of a new field in synthetic chemistry - the direct synthesis of coordination and organometallic compounds from zero-valent metals. Particular aspects of the above problem have been described in a series of reviews and monographs. However, on the whole these main parts of the direct synthesis of metal complexes has not been dealt with in the review and monograph publications on coordination chemistry. So, the main objective of this book is to analyze, discuss and generalize the existing information in the area of direct reactions leading to the coordination and organometallic reactions. Some methods of direct synthesis have been developed in the former USSR (in particular, a lot of works on cryosynthesis, pioneered (1972-1973) and recent works on electrosynthesis) but, in spite of their novelty and/or wide applicability, they are practically unknown elsewhere due to the language barrier. Thus, another objective of this book is to acquaint the readers with the mentioned achievements. Every chapter contains the tables which describe all the reported data on direct reaction between metal atoms, metal particles or bulk metals with (in)organic ligans. There are some illustrations also (for example, the scheme of the reactor for gas-phase reaction between metal small particles and &bgr;-diketones).

Direct Synthesis of Coordination and Organometallic Compounds

Direct Synthesis of Coordination and Organometallic Compounds
  • Author : A.D. Garnovskii,B.I. Kharisov
  • Publisher : Elsevier
  • Release Date : 1999-08-13
  • Total pages : 244
  • ISBN : 9780080530444
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Summary : This book is devoted to the interaction between elemental metals and (in)organic ligands in different reaction conditions. Metals could be activated for further reactions as cryosynthesis, electrosynthesis and tribosynthesis, some of them with or without ultrasonic and microwave treatment. The kinetics of metal dissolution in various non-aqueous media is ...

Direct Synthesis of Metal Complexes

Direct Synthesis of Metal Complexes
  • Author : B.I. Kharisov
  • Publisher : Elsevier
  • Release Date : 2018-04-19
  • Total pages : 468
  • ISBN : 9780080530444
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Summary : Direct Synthesis of Metal Complexes provides in-depth coverage of the direct synthesis of coordination and organometallic compounds. The work is primarily organized by methods, but also covers highly relevant complexes, such as metal-polymer coordination compounds. This updated reference discusses recent developments in cryosynthesis, electrosynthesis, and tribosynthesis (popular as it doesn’...

Carbonylation

Carbonylation
  • Author : H.M. Colquhoun,D.J. Thompson,M.V. Twigg
  • Publisher : Springer Science & Business Media
  • Release Date : 2013-06-29
  • Total pages : 296
  • ISBN : 9780080530444
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Summary : Since the publication of our earlier book on transition metal mediated organic synthesis, * there has been a widespread increase of interest in this topic, and transition metal based methodology has become firmly established in many areas of organic chemistry. The direct, catalytic formation of organic carbonyl compounds using carbon monoxide ...

The Development of a General Direct Synthesis of Metallocarboranes

The Development of a General Direct Synthesis of Metallocarboranes
  • Author : William John Evans
  • Publisher : Unknown
  • Release Date : 1973
  • Total pages : 364
  • ISBN : 9780080530444
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Summary : Download or read online The Development of a General Direct Synthesis of Metallocarboranes written by William John Evans, published by which was released on 1973. Get The Development of a General Direct Synthesis of Metallocarboranes Books now! Available in PDF, ePub and Kindle....

Russian Journal of Coordination Chemistry

Russian Journal of Coordination Chemistry
  • Author : Anonim
  • Publisher : Unknown
  • Release Date : 1999
  • Total pages : 212
  • ISBN : 9780080530444
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Summary : Download or read online Russian Journal of Coordination Chemistry written by , published by which was released on 1999. Get Russian Journal of Coordination Chemistry Books now! Available in PDF, ePub and Kindle....

The Direct Synthesis of Optically Active Complexes of the Alkaline Earth Metals

The Direct Synthesis of Optically Active Complexes of the Alkaline Earth Metals
  • Author : Billy Thomas Upchurch
  • Publisher : Unknown
  • Release Date : 1967
  • Total pages : 114
  • ISBN : 9780080530444
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Summary : Download or read online The Direct Synthesis of Optically Active Complexes of the Alkaline Earth Metals written by Billy Thomas Upchurch, published by which was released on 1967. Get The Direct Synthesis of Optically Active Complexes of the Alkaline Earth Metals Books now! Available in PDF, ePub and Kindle....

Spectral Methods in Transition Metal Complexes

Spectral Methods in Transition Metal Complexes
  • Author : K. Sridharan
  • Publisher : Elsevier
  • Release Date : 2016-02-13
  • Total pages : 202
  • ISBN : 9780080530444
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Summary : Spectral Methods in Transition Metal Complexes provides a conceptual understanding on how to interpret the optical UV-vis, vibrational EPR, and NMR spectroscopy of transition metal complexes. Metal complexes have broad applications across chemistry in the areas of drug discovery, such as anticancer drugs, sensors, special materials for specific requirements, and ...

Russian Chemical Reviews

Russian Chemical Reviews
  • Author : Anonim
  • Publisher : Unknown
  • Release Date : 2005
  • Total pages : 212
  • ISBN : 9780080530444
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Summary : Download or read online Russian Chemical Reviews written by , published by which was released on 2005. Get Russian Chemical Reviews Books now! Available in PDF, ePub and Kindle....

Transition metal Organometallics In Organic Synthesis

Transition metal Organometallics In Organic Synthesis
  • Author : Howard Alper
  • Publisher : Academic Press
  • Release Date : 2012-12-02
  • Total pages : 270
  • ISBN : 9780080530444
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Summary : Transition Metal Organometallics in Organic Synthesis: Volume I reviews the literature in the field of organic synthesis with a focus on the most effective synthetic transformations. The text covers topics such as the general considerations in organic synthesis, C-C and C-X bond formations, and the isomerization and reorganization reactions of ...

The Coordination Chemistry of D and F block Metal Complexes of 1 2 benzenediolenes

The Coordination Chemistry of D  and F block Metal Complexes of 1 2 benzenediolenes
  • Author : Stephen Robert Sofen
  • Publisher : Unknown
  • Release Date : 1979
  • Total pages : 276
  • ISBN : 9780080530444
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Summary : Download or read online The Coordination Chemistry of D and F block Metal Complexes of 1 2 benzenediolenes written by Stephen Robert Sofen, published by which was released on 1979. Get The Coordination Chemistry of D and F block Metal Complexes of 1 2 benzenediolenes Books now! Available in PDF, ePub and Kindle....

Book of Abstracts

Book of Abstracts
  • Author : American Chemical Society. Meeting,American Chemical Society
  • Publisher : Unknown
  • Release Date : 1976
  • Total pages : 212
  • ISBN : 9780080530444
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Summary : Download or read online Book of Abstracts written by American Chemical Society. Meeting,American Chemical Society, published by which was released on 1976. Get Book of Abstracts Books now! Available in PDF, ePub and Kindle....

INIS Atomindex

INIS Atomindex
  • Author : Anonim
  • Publisher : Unknown
  • Release Date : 1985
  • Total pages : 212
  • ISBN : 9780080530444
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Summary : Download or read online INIS Atomindex written by , published by which was released on 1985. Get INIS Atomindex Books now! Available in PDF, ePub and Kindle....

Patai s Guide to the Chemistry of Functional Groups

Patai s Guide to the Chemistry of Functional Groups
  • Author : Saul Patai
  • Publisher : Unknown
  • Release Date : 1989-05-05
  • Total pages : 455
  • ISBN : 9780080530444
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Summary : In this handy reference guide and index to the volumes in the The Chemistry of Functional Groups series, all volumes are indexed and cross-referenced (according to related and complementary chapters). Users of the series will find this volume indispensable for finding information quickly and easily....

Indian Journal of Chemistry

Indian Journal of Chemistry
  • Author : Anonim
  • Publisher : Unknown
  • Release Date : 2006
  • Total pages : 212
  • ISBN : 9780080530444
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Summary : Download or read online Indian Journal of Chemistry written by , published by which was released on 2006. Get Indian Journal of Chemistry Books now! Available in PDF, ePub and Kindle....

I Synthesis Characterization and Reactivity of Platinum II Metal Complexes of Phosphorus containing Mesocycles II Bifunctional Phosphines as Reagents in Carbon Tetrachloride promoted Chlorination Reactions

I  Synthesis  Characterization and Reactivity of Platinum II  Metal Complexes of Phosphorus containing Mesocycles  II  Bifunctional Phosphines as Reagents in Carbon Tetrachloride promoted Chlorination Reactions
  • Author : Susan Deborah Toto
  • Publisher : Unknown
  • Release Date : 1989
  • Total pages : 448
  • ISBN : 9780080530444
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Summary : Download or read online I Synthesis Characterization and Reactivity of Platinum II Metal Complexes of Phosphorus containing Mesocycles II Bifunctional Phosphines as Reagents in Carbon Tetrachloride promoted Chlorination Reactions written by Susan Deborah Toto, published by which was released on 1989. Get I Synthesis Characterization and Reactivity of Platinum II Metal ...